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The Influence of Uranyl Hydrolysis and Multiple Site-Binding Reactions on Adsorption of U(VI) to Montmorillonite
Montmorillonite Uranyl
2011/12/28
Adsorption of uranyl to SWy-1 montmorillonite was evaluated experimentally and results were modeled to identify likely surface complexation reactions responsible for removal of uranyl from solution. U...
Molecular Structure and Binding Sites of Cobalt(II) Surface Complexes on Kaolinite from X-ray Absorption Spectroscopy
Cobalt EXAFS Kaolinite Sorption Surface complex
2011/12/29
X-ray absorption spectroscopy (XAS) was used to determine the local molecular environment of Co(II) surface complexes sorbed on three different kaolinites at ambient temperature and pressure in contac...
Modified Clays for the Adsorption of Environmental Toxicants: Binding of Chlorophenols to Pillared, Delaminated, and Hydroxy-Interlayered Smectites
Adsorption Chlorophenol Delaminated smectite Hydroxy-Al Laponite Pillared smectite Smectite Toxicants
2012/1/9
Due to their unique polarity, pore-size distribution, and high surface areas, pillared and delaminated clays are potentially useful materials for the adsorption of environmental toxicants. To determin...
Tris(Acetylacetonato)Silicon(IV) Binding to Montmorillonite and Hydrolysis to Interlayer Silicic Acid
Hydrolysis Montmorillonite Pillared interlayer complex Si(acac)3+ Silicic acid
2012/2/2
The reactions of the tris(acetylacetonato)silicone(IV) cation (Si(acac)3+) with Na+-, Mg2+-, and Co2+-exchange forms of hectorite and montmorillonite have been investigated to understand better the fo...