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Analysis of 13C and 18O isotope data of CO2 in CARIBIC aircraft samples as tracers of upper troposphere/lower stratosphere mixing and the global carbon cycle
13C and 18O isotope data CO2 CARIBIC aircraft samples the global carbon cycle
2010/9/21
The project CARIBIC (http://caribic-atmospheric.com) aims to study atmospheric chemistry and transport by regularly measuring many compounds in the free troposphere and the upper troposphere/lowermost...
Pressure dependence of the deuterium isotope effect in the photolysis of formaldehyde by ultraviolet light
the deuterium isotope effect the photolysis of formaldehyde ultraviolet light
2010/8/12
The pressure dependence of the relative photolysis rate of HCHO vs. HCDO has been investigated for the first time, using a photochemical reactor at the University of Copenhagen. The dissociation of HC...
Trend in ice moistening the stratosphere – constraints from isotope data of water and methane
ice moistening isotope data water methane
2010/1/18
Water plays a major role in the chemistry and radiative budget of the stratosphere. Air enters the stratosphere predominantly in the tropics, where the very low temperatures around the tropopause cons...
How did Marine Isotope Stage 3 and Last Glacial Maximum climates differ? – Perspectives from equilibrium simulations
Marine Isotope Stage 3 Last Glacial Maximum
2009/12/3
Dansgaard-Oeschger events occurred frequently during Marine Isotope Stage 3 (MIS3), as opposed to the following MIS2 period, which included the Last Glacial Maximum (LGM). Transient climate model sim...
Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling
nitrate stable isotope signal snow atmosphere East Antarctica reactive nitrogen cycling
2009/11/19
The nitrogen (δ15N) and triple oxygen (δ17O and δ18O) isotopic composition of nitrate (NO3−) was measured year-round in the atmosphere and snow pits at Dome C, Antarctica (DC, 75.1° S, 123.3° E)...
A consistent molecular hydrogen isotope chemistry scheme based on an independent bond approximation
molecular hydrogen isotope chemistry scheme independent bond approximation
2009/11/19
The isotopic composition of molecular hydrogen (H2) produced by photochemical oxidation of methane (CH4) and Volatile Organic Compounds (VOCs) is a key quantity in the global isotope budget of (H2). T...
New insight into the atmospheric chloromethane budget gained using stable carbon isotope ratios
atmospheric chloromethane budget stable carbon isotope ratios
2009/2/17
Atmospheric chloromethane (CH3Cl) plays an important role in stratospheric ozone destruction, but many uncertainties still exist regarding strengths of both sources and sinks and the processes leading...
Signature of Arctic surface ozone depletion events in the isotope anomaly (Δ17O) of atmospheric nitrate
Arctic surface ozone isotope anomaly atmospheric nitrate
2008/12/3
We report the first measurements of the oxygen isotope anomaly of atmospheric inorganic nitrate from the Arctic. Nitrate samples and complementary data were collected at Alert, Nunavut, Canada (82°30 ...
Investigations of the photochemical isotope equilibrium between O2, CO2 and O3
photochemical isotope equilibrium O2 CO2 O3
2008/11/28
Contrary to tropospheric CO2 whose oxygen isotopic composition follows a standard mass dependent relationship, i.e. δ17O~0.5δ18O, stratospheric CO2 is preferentially enriched in 17O, leading to a stri...